Urea

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Technical Specifications

CH4N2O
Molar mass 60.056 g·mol−1
Appearance White solid
Density 1.32 g/cm3
Melting point 133 to 135 °C (271 to 275 °F; 406 to 408 K)
1079 g/L (20 °C)
1670 g/L (40 °C)
2510 g/L (60 °C)
4000 g/L (80 °C)
Solubility 500 g/L glycerol

50g/L ethanol
~4 g/L acetonitrile

Basicity (pKb) 13.9[4]
-33.4·10−6 cm3/mol

Application & Dosage

  • More than 90% of world industrial production of urea is destined for use as a nitrogen-release fertilizer. Urea has the highest nitrogen content of all solid nitrogenous fertilizers in common use. Therefore, it has the lowest transportation costs per unit of nitrogen nutrient.
  • Urea is a raw material for the manufacture of two main classes of materials: urea-formaldehyde resins and urea-melamine-formaldehyde used in marine plywood.
  • Urea is used in SNCR and SCR reactions to reduce the NOx pollutants in exhaust gases from combustion from Diesel, dual fuel, and lean-burn natural gas engines. The BlueTec system, for example, injects a water-based urea solution into the exhaust system.
  • Urea in concentrations up to 10 M is a powerful protein denaturant as it disrupts the noncovalent bonds in the proteins. This property can be exploited to increase the solubility of some proteins. A mixture of urea and choline chloride is used as a deep eutectic solvent (DES), a substance similar to ionic liquid. When used in a deep eutectic solvent, urea does not denature the proteins that are solubilized.
  • Urea-containing creams are used as topical dermatological products to promote rehydration of the skin. Urea 40% is indicated for psoriasis, xerosis, onychomycosis, ichthyosis, eczema, keratosis, keratoderma, corns, and calluses.
  • An ingredient in diesel exhaust fluid (DEF), which is 32.5% urea and 67.5% de-ionized water. DEF is sprayed into the exhaust stream of diesel vehicles to break down dangerous NOx emissions into harmless nitrogen and water.
  • A component of animal feed, providing a relatively cheap source of nitrogen to promote growth
  • A non-corroding alternative to rock salt for road de-icing. It is often the main ingredient of pet friendly salt substitutes although it is less effective than traditional rock salt or calcium chloride.
  • A main ingredient in hair removers such as Nair and Veet
  • A browning agent in factory-produced pretzels
  • An ingredient in some skin cream, moisturizers, hair conditioners, and shampoos
  • A cloud seeding agent, along with other salts.
  • A flame-proofing agent, commonly used in dry chemical fire extinguisher charges such as the urea-potassium bicarbonate mixture
  • An ingredient in many tooth whitening products.
  • An ingredient in dish soap
  • Along with diammonium phosphate, as a yeast nutrient, for fermentation of sugars into ethanol
  • A nutrient used by plankton in ocean nourishment experiments for geoengineering purposes
  • As an additive to extend the working temperature and open time of hide glue
  • As a solubility-enhancing and moisture-retaining additive to dye baths for textile dyeing or printing
  • As an optical parametric oscillator in nonlinear optics

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