Antifoam Defoamer PPG

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RIGS Oil Field-34

Antifoam Defoamer PPG

SKU: RXSOL-34-2066-220
Polypropylene Glycol (PPG) Based Defoamer RXSOL PPG-Based Defoamer for Hydraulic Fracturing Operations, Highly effective liquid antifoam formulated for controlling foaming
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Technical Specifications

Technical Specifications

Development targets only; not certified RXSOL product specifications.

Property

Proposed Target

Appearance

Clear to slightly hazy liquid

Colour

Colourless to pale yellow

Specific Gravity at 25°C

0.98–1.05

Active Polyether Content

90% nominal

Water Solubility

Grade-dependent; test dispersibility

Silicone Content

None intentionally added

Viscosity

Establish after pilot batch

Storage Stability

No separation under defined test conditions

Application & Dosage

The foaming tendency of seawater in distillation plants is unpredictable. It is generally thought that foam is formed when organic compounds are concentrated in the brine, giving rise to surface active effects which increase the liquid film strength at phase interfaces. Antifoam Defoamer AF10 is not soluble in water. At use concentrations (0.05 - 0.1 mg/l) Antifoam Defoamer AF10 forms a micro-emulsion and during evaporation is incorporated into the surface liquid film of bubbles where it acts as a surfactant and reduces the film strength. The result is that the film readily ruptures and a stable foam does not form. In this way a uniform boiling or flashing action is achieved and carry-over is minimised.

Where to use ANTIFOAM AF10 for foam knockdown?

Desalination Plants
  • Reverse Osmosis (RO) Plants
  • Multi-Stage Flash (MSF) Plants
  • Multi-Effect Distillation (MED) Plants
  • Hybrid Desalination Facilities
Seawater Systems
  • Intake Channels
  • Seawater Make-up Lines
  • Pumping Stations
  • Equalization Basins
  • Clarifiers
  • Dissolved Air Flotation (DAF) Units
  • Pretreatment Systems
Industrial Water Systems
  • Power Plant Cooling Water Intakes
  • Refinery Seawater Systems
  • Petrochemical Facilities
  • Offshore Platforms
  • LNG Terminals

Suggested Dosage for Fracturing Fluids

For initial laboratory screening:

Application

Trial Dosage

Low-foaming freshwater systems

25–50 ppm

Surfactant-containing slickwater

50–100 ppm

High-TDS brine systems

100–200 ppm

Severe foaming

Determine by dose-response testing

These are proposed screening concentrations, not verified field dosage recommendations. A comparable commercial brine defoamer uses low-volume dosages but has a different silicone-based chemistry.

Suggested 100 kg Manufacturing Formulation

The following is a laboratory-development starting formulation, not a field-qualified commercial recipe.

Raw Material

Quantity (kg)

Function

Polypropylene Glycol PPG-2000

55.0

Primary foam-control agent

Polypropylene Glycol PPG-4000

20.0

Foam suppression and persistence

EO/PO Block Copolymer, low-foam grade

15.0

Secondary foam-control agent

Dipropylene Glycol

10.0

Carrier and viscosity adjustment

Total

100.0

 

The exact EO/PO grade is critical because some polyether products promote foaming rather than suppress it. PPG is also used for other purposes in fracturing fluids, so its presence alone does not establish defoaming performance.

 
 
 
 
Antifoam Defoamer AF10 can be used to control foaming in all types of seawater distillation plant and is particularly suitable for use in multi-stage flash plants. Antifoam Defoamer AF10 is a formulated product containing ethylene oxide / propylene oxide block copolymer.  Antifoam Defoamer AF10 is typically dosed as a 1% w/w emulsion in distillate prepared as follows:
  • Add 50% - 70% of required distillate volume into dosing tank;
  • Start the dosing tank agitator/mixer;
  • Add the required Antifoam Defoamer AF10 volume into the dosing tank;
  • Add the remaining volume of distillate to give the required concentration of Antifoam Defoamer AF10 solution;
  • Continue agitation for a further 10 - 15 minutes;
  • The resulting emulsion will be stable and will not normally separate

The dose level required will depend on the quality of the seawater feed (e.g. dissolved organics, suspended solids) but is typically found to be in the range 0.05 to 0.1 mg/l and is subject to optimisation as operating experience is gained. Dose level is not dependent on operating temperature of the distillation plant. Recommended injection points are either into the seawater make-up line after any external de-aeration and decarbonation equipment, or into the recycle brine stream at a suitable point after the blowdown and typically into the discharge of the recycle brine pump.

General-purpose antifoams have a wide range of applicability, but not all of them are suitable for use in the treatment. Some foam control agents can aggravate the problem. Foam control in gas scrubbers is only one of the process parameters to be monitored. It is equally important to prevent or slow the fouling of the unit, because dismantling of the gas-scrubbing units is manually intensive. Incorrectly specified antifoams can easily lead to increased fouling and clogging, particularly in the heat exchangers. Momentive Performance Materials RXSOL antifoams are designed to provide foam control with a minimum of such problems.

 

Dosing for Desalination plants/aqueous systems

Actual dosage requirements depends upon:
  • Organic loading
  • Algal concentration
  • Turbulence level
  • Intake water quality
  • Seasonal variations
Application Condition Recommended Dosage
Normal Operation 0.5 - 5 ppm
Moderate Foaming 2 - 10 ppm
Severe Foaming 5 - 20 ppm
Shock Treatment 10 - 50 ppm

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